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Molecular structure, spectroscopic properties (FT-IR, Micro-Raman, and UV-vis), and DFT calculations of minaprine

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dc.creator Bahceli, S.
dc.creator Gokce, H.
dc.date 2014-07-01T00:00:00Z
dc.date.accessioned 2021-12-03T12:03:25Z
dc.date.available 2021-12-03T12:03:25Z
dc.identifier d7cf3b34-6636-47e8-9b23-438bea9c83bf
dc.identifier 10.1134/s0030400x14040110
dc.identifier https://avesis.sdu.edu.tr/publication/details/d7cf3b34-6636-47e8-9b23-438bea9c83bf/oai
dc.identifier.uri http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/95199
dc.description Molecular geometry, experimental vibrational wavenumbers, electronic properties, and quantum chemical calculations of minaprine (C17H22N4O center dot 2HCl), (with synonym, dihydrochloride salt of N-(4-methyl-6-phenyl-3-pyridazinyl)-4-morpholineethamine) which is widely used as a psychotropic drug at medicinal treatment, in the ground state by using density functional theory (DFT/B3LYP) method with 6-31++G(d,p) basis set have been presented for the first time. The comparison of the observed fundamental vibrational frequencies were in a very good agreement with the experimental data. Furthermore, UV-vis TD-DFT calculations, the highest occupied molecular orbitals (HOMO-1, HOMO), lowest unoccupied molecular orbitals (LUMO, LUMO + 1), molecular electrostatic potential (MEP) surface, atomic charges and thermodynamic properties of minaprine molecule have been theoretically calculated and simulated at the mentioned level.
dc.language eng
dc.rights info:eu-repo/semantics/closedAccess
dc.title Molecular structure, spectroscopic properties (FT-IR, Micro-Raman, and UV-vis), and DFT calculations of minaprine
dc.type info:eu-repo/semantics/article


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