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Vibrational spectroscopic investigation of p-, m- and o-nitrobenzonitrile by using Hartree-Fock and density functional theory

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dc.creator Ucun, F.
dc.creator Sert, Y.
dc.date 2013-08-01T00:00:00Z
dc.date.accessioned 2021-12-03T12:04:46Z
dc.date.available 2021-12-03T12:04:46Z
dc.identifier ee1ecd5f-6b42-4ab5-8bc1-8d904a8f11ef
dc.identifier 10.1007/s12648-013-0293-5
dc.identifier https://avesis.sdu.edu.tr/publication/details/ee1ecd5f-6b42-4ab5-8bc1-8d904a8f11ef/oai
dc.identifier.uri http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/95696
dc.description In the present work, the theoretical vibrational spectra of p-, m- and o-nitrobenzonitrile molecules have been analyzed. The harmonic vibrational frequencies and geometric parameters (bond lengths and bond angles) of these molecules have been calculated using ab initio Hartree-Fock and density functional theory methods with 6-311++G(d,p) basis set by Gaussian 03 W, for the first time. Assignments of the vibrational frequencies have been performed by potential energy distribution by using VEDA 4 program. The optimized geometric parameters and harmonic vibrational frequencies have been compared with the corresponding experimental data and seen to be in a good agreement with each other. Also, the highest occupied molecular orbital and lowest unoccupied molecular orbital energies have been obtained.
dc.language eng
dc.rights info:eu-repo/semantics/closedAccess
dc.title Vibrational spectroscopic investigation of p-, m- and o-nitrobenzonitrile by using Hartree-Fock and density functional theory
dc.type info:eu-repo/semantics/article


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