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Determination of Dissociation Constants of Some Hydroxylated Benzoic and Cinnamic Acids in Water from Mobility and Spectroscopic Data Obtained by CE-DAD

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dc.creator Ozkorucuklu, Sabriye P.
dc.creator Alsancak, Gueleren
dc.creator Fonrodona, Gemma
dc.creator Barron, Dolores
dc.creator Barbosa, Jose
dc.creator Beltran, Jose L.
dc.date 2009-03-01T01:00:00Z
dc.date.accessioned 2021-12-03T12:05:00Z
dc.date.available 2021-12-03T12:05:00Z
dc.identifier f2111c8d-d778-4100-b545-4fed1b923354
dc.identifier 10.1021/je800595x
dc.identifier https://avesis.sdu.edu.tr/publication/details/f2111c8d-d778-4100-b545-4fed1b923354/oai
dc.identifier.uri http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/95784
dc.description In this study, the dissociation constants of a series of phenolic acids, including benzoic acid, four hydroxylated derivatives (p-hydroxybenzoic, protocatechuic, vanillic, and gallic), and four hydroxylated cinnamic acid derivatives (p-coumaric, caffeic, ferulic, and sinapinic) have been determined in water by capillary electrophoresis (CE) from the electrophoretic mobilities at different pH value. The pK(a) values have also been obtained from the absorbance spectra at the maximum of the electrophoretic peaks, which were measured with a diode-array detector (CE-DAD methodology). The pK(a) values obtained from both methodologies (CE and CE-DAD) have been compared with those previously published in the literature and also with the values predicted by the SPARC online pK(a) calculator.
dc.language eng
dc.rights info:eu-repo/semantics/closedAccess
dc.title Determination of Dissociation Constants of Some Hydroxylated Benzoic and Cinnamic Acids in Water from Mobility and Spectroscopic Data Obtained by CE-DAD
dc.type info:eu-repo/semantics/article


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