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Synthesis and characterization of new ketooximes and their complexes

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dc.creator Karipcin, F.
dc.creator Arabali, F.
dc.date 2006-09-01T00:00:00Z
dc.date.accessioned 2021-12-03T12:05:25Z
dc.date.available 2021-12-03T12:05:25Z
dc.identifier f939935a-2fd4-4983-8c84-aed79e85bb1e
dc.identifier 10.1134/s0036023606090105
dc.identifier https://avesis.sdu.edu.tr/publication/details/f939935a-2fd4-4983-8c84-aed79e85bb1e/oai
dc.identifier.uri http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/95937
dc.description The starting point of the research was the reaction of chloroacetyl chloride with biphenyl in the presence of aluminum chloride. 4-Biphenylhydroximoyl chloride (HL) was obtained by reacting synthesized 4-(chloroacetyl)biphenyl with alkyl nitride. Four new substituted 4-(alkylaminoisonitrosoacetyl)biphenyles (ketooximes) were prepared by reacting 4-biphenylhydroximoyl chloride with corresponding amines in EtOH. The following amines were used for ligands: p-toluidine, p-chloroaniline, pyrrolidine, and 4-aminoacetophenone. Mononuclear complexes with a metal-ligand ratio of 1: 2 were prepared using cadmium(II), cobalt(II), copper(II), nickel(II), lead(II), and zinc(II) salts. These compounds have been characterized by elemental analyses, AAS, infrared spectra and magnetic susceptibility measurements. The ligands have been further characterized by H-1 NMR. The results suggest that the ketooximes act as bidentate ligands which bond metal ions through the oxime and carbonyl oxygen.
dc.language eng
dc.rights info:eu-repo/semantics/closedAccess
dc.title Synthesis and characterization of new ketooximes and their complexes
dc.type info:eu-repo/semantics/article


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