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Scheelite-type BaMoO4 and BaWO4 based dye sensitized photocatalytic hydrogen evolution by water splitting

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dc.creator Aslan, Emre
dc.creator HATAY PATIR, İMREN
dc.creator Keles, Ali
dc.creator Yanalak, Gizem
dc.creator ÖZEL, FARUK
dc.creator ÖZEN, Abdurrahman
dc.creator SARILMAZ, ADEM
dc.date 2022-09-01T00:00:00Z
dc.date.accessioned 2023-01-09T12:03:47Z
dc.date.available 2023-01-09T12:03:47Z
dc.identifier 6b06a02f-1e1d-43b9-9cdd-459053aa4222
dc.identifier 10.1016/j.jpcs.2022.110821
dc.identifier https://avesis.sdu.edu.tr/publication/details/6b06a02f-1e1d-43b9-9cdd-459053aa4222/oai
dc.identifier.uri http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/97964
dc.description Nowadays, the development of cost-effective and stable catalyst has greatly drawn attention for electrocatalytic and photocatalytic hydrogen evolution reactions. Herein, photocatalytic hydrogen evolution has been investigated by using BaMoO4 and BaWO4 catalysts in the presence of triethanolamine and eosin-Y as a sacrificial agent and visible-light-sensitizer, respectively. These refractory metal-based oxides prepared by solid phase synthesis procedure have been characterized by structural, morphological, optical and electrochemical techniques, which are obtained with high crystallinity and adequate stoichiometric ratios. While the hydrogen evolution rate of BaMoO4 is higher than BaWO4 in the first hours of photocatalytic reaction, BaWO4 displays more stable activity for hydrogen evolution, which is reached 3.37 mmolg(-1) after the 8 h of photocatalytic reaction. The proposed mechanism of dye-sensitized photocatalytic hydrogen evolution is explained by data obtained from optical and electrochemical properties.
dc.language eng
dc.rights info:eu-repo/semantics/closedAccess
dc.title Scheelite-type BaMoO4 and BaWO4 based dye sensitized photocatalytic hydrogen evolution by water splitting
dc.type info:eu-repo/semantics/article


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