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Preparation and Characterization of Poly(lactic acid)-Based Poly(ethylene glycol) and Daphne Essential Oil-Loaded Smart Nanofibers for Thermal Protection

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dc.creator COŞKUN, YALÇIN
dc.creator GungorErtugral, Tugba
dc.creator ORAL, AYHAN
dc.creator ULUSOY, Seyhan
dc.date 2024-10-22T00:00:00Z
dc.date.accessioned 2025-02-25T10:18:36Z
dc.date.available 2025-02-25T10:18:36Z
dc.identifier 24d994a8-a5b7-4b80-a57a-2998796b2bc9
dc.identifier 10.1021/acsomega.3c07720
dc.identifier https://avesis.sdu.edu.tr/publication/details/24d994a8-a5b7-4b80-a57a-2998796b2bc9/oai
dc.identifier.uri http://acikerisim.sdu.edu.tr/xmlui/handle/123456789/99085
dc.description Phase change material (PCM) stores latent heat energy, and poly(ethylene glycol) (Mw: 4000) (PEG 4000) is also a solid-liquid PCM. PEG and poly(lactic acid) (PLA) polymers are biodegradable. Essential oils are known as plant extracts with antimicrobial properties. In this study, daphne essential oil (DEO) obtained by the distillation method and PLA/PEG/DEO composite nanofibers were prepared by the electrospinning method with PLA, PEG 4000, and daphne (Laurus nobilis L.) essential oil in certain ratios (100/100/20, 100/120/20, and 100/150/20). DEO showed an antibacterial effect against Staphylococcus aureus and Escherichia coli bacteria. Thermal behaviors of the nanofibers were characterized by differential scanning calorimetry and thermogravimetric analysis. Morphological features were observed by scanning electronic microscopy (SEM), crystal behavior by X-ray diffraction analysis, and molecular structures were examined by Fourier transform infrared spectroscopy. Essential oil composition was determined by GC-MS. The thermal decomposition temperatures of the nanofibers were found between 250 and 276 °C, and the latent heat storage energies of nanofibers were 69.06, 86.76, and 96.39 J g-1 at temperatures 59.0 and 54.37 °C. High PCM added fiber was observed as 182 nm diameter with 3.264 μm diameter spheres. The produced nanofiber matrix has the potential to be used in applications such as medicine, textile, and hot food logistics.
dc.language eng
dc.rights info:eu-repo/semantics/closedAccess
dc.title Preparation and Characterization of Poly(lactic acid)-Based Poly(ethylene glycol) and Daphne Essential Oil-Loaded Smart Nanofibers for Thermal Protection
dc.type info:eu-repo/semantics/article


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